4-[(4-Bromo­phenyl)amino]-2-methyl­idene-4-oxo­butanoic acid

نویسندگان

  • B. Narayana
  • Prakash S. Nayak
  • Balladka K. Sarojini
  • Jerry P. Jasinski
چکیده

In the title compound, C11H10BrNO3, two independent mol-ecules (A and B) crystallize in the asymmetric unit. The dihedral angles between the mean planes of the 4-bromo-phenyl ring and amide group are 24.8 (7) in mol-ecule A and 77.1 (6)° in mol-ecule B. The mean plane of the methyl-idene group is further inclined by 75.6 (4) in mol-ecule A and 72.5 (6)° in mol-ecule B from that of the amide group. In the crystal, N-H⋯O hydrogen bonds formed by amide groups and O-H⋯O hydrogen bonds formed by carb-oxy-lic acid groups are observed and supported additionally by weak C-H⋯O inter-actions between the methyl-idene and amide groups. Together, these link the mol-ecules into chains of dimers along [110] and form R 2 (2)(8) graph-set motifs.

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عنوان ژورنال:

دوره 70  شماره 

صفحات  -

تاریخ انتشار 2014